Carbon isotope evidence for CAM photosynthesis in the Mesozoic

Crassulacean acid metabolism (CAM) photosynthesis, a flexible adaptation to water‐stress, has not been shown to occur before the Pleistocene, despite suggestions that CAM first evolved in the Mesozoic or earlier. Here we report on multiple (≥7) positive organic carbon isotope excursions (δ¹³C_org > ?20 ‰ ) in Late Triassic and Early Jurassic (c. 200 Ma) sedimentary rocks from an arid terrestrial ecosystem in South Africa. These excursions are interpreted as evidence of the episodic dominance of CAM plants in response to heightened aridity in the heartland of Gondwana, and hint at climatic instability in a greenhouse world.     

A comparison of the sedimentary records of the 1960 and 2010 great Chilean earthquakes in 17 lakes: Implications for quantitative lacustrine palaeoseismology

Seismically‐induced event deposits embedded in the sedimentary infill of lacustrine basins are highly useful for palaeoseismic reconstructions. Recent, well‐documented, great megathrust earthquakes provide an ideal opportunity to calibrate seismically‐induced event deposits for lakes with different characteristics and located in different settings. This study used 107 short sediment cores to investigate the sedimentary impact of the 1960 M_w 9·5 Valdivia and the 2010 M_w 8·8 Maule earthquakes in 17 lakes in South‐Central Chile (i.e. lakes Negra, Lo Encañado, Aculeo, Vichuquén, Laja, Villarrica, Calafquén, Pullinque, Pellaifa, Panguipulli, Neltume, Riñihue, Ranco, Maihue, Puyehue, Rupanco and Llanquihue). A combination of image analysis, magnetic susceptibility and grain‐size analysis allows identification of five types of seismically‐induced event deposits: (i) mass‐transport deposits; (ii) in situ deformations; (iii) lacustrine turbidites with a composition similar to the hemipelagic background sediments (lacustrine turbidites type 1); (iv) lacustrine turbidites with a composition different from the background sediments (lacustrine turbidites type 2) and (v) megaturbidites. These seismically‐induced event deposits were compared to local seismic intensities of the causative earthquakes, eyewitness reports, post‐earthquake observations, and vegetation and geomorphology of the catchment and the lake. Megaturbidites occur where lake seiches took place. Lacustrine turbidites type 2 can be the result of: (i) local near‐shore mass wasting; (ii) delta collapse; (iii) onshore landslides; (iv) debris flows or mudflows; or (v) fluvial reworking of landslide debris. On the contrary, lacustrine turbidites type 1 are the result of shallow mass wasting on sublacustrine slopes covered by hemipelagic sediments. Due to their more constrained origin, lacustrine turbidites type 1 are the most reliable type of seismically‐induced event deposits in quantitative palaeoseismology, because they are almost exclusively triggered by earthquake shaking. Moreover, they most sensitively record varying seismic shaking intensities. The number of lacustrine turbidites type 1 linearly increases with increasing seismic intensity, starting with no lacustrine turbidites type 1 at intensities between V½ and VI and reaching 100% when intensities are higher than VII½. Combining different types of seismically‐induced event deposits allows the reconstruction of the complete impact of an earthquake.     

Benthic species as mud patrol - modelled effects of bioturbators and biofilms on large-scale estuarine mud and morphology

Sediment-stabilizing and -destabilizing organisms, i.e. microphytobenthos (biofilms) and macrozoobenthos (bioturbators), affect the erodibility of muddy sediments, potentially altering large-scale estuarine morphology. Using a novel eco-morphodynamic model of an idealized estuary, we investigate eco-engineering effects of microphytobenthos and two macrozoobenthic bioturbators. Local mud erodibility is based on species pattern predicted through hydrodynamics, soil mud content, competition and grazing. Mud resuspension and export is enhanced under bioturbation and prevented under biostabilization through respective exposure and protection of the supra- and intertidal. Bioturbation decreases mud thickness and bed elevations, which increases net mud fluxes. Microphytobenthos reduces erosion, leading to a local mud increase of intertidal sediments. In multi-species scenarios, an effective mud-prone bioturbator strongly alters morphology, exceeding that of a more abundant sand-prone moderate species, showing that morphological change depends on species traits as opposed to abundance. Altering their habitat, the effective mud-prone bioturbator facilitates expansion of the sand-prone moderate bioturbator. Grazing and species competition favor species distributions of dominant bioturbators. Consequently, eco-engineering affects habitat conditions while species interactions determine species dominance. Our results show that eco-engineering species determine the mud content of the estuary, which suggests large effects on the morphology of estuaries with aggravating habitat degradation.     

Multidirectional,synchronously‐triggered seismo‐turbidites and debrites revealed by X‐ray computed tomography (CT)

On 21 April 2007, a M_w 6·2 earthquake struck Aysén fjord (Chilean Patagonia) and caused onshore and offshore mass movements which triggered tsunamis and density flows in the fjord. To better understand the facies successions in, and the intercalation of, the density‐flow deposits, a study was made of the 2007 deposits in 22 short sediment cores taken in the inner Aysén fjord. By combining grain‐size analysis with X‐ray computed tomography scanning, it was possible to demonstrate that the encountered facies correspond to classical divisions of debrites and turbidites. The single‐event deposits consist of a succession of several sub‐deposits deposited under different flow directions and can be interpreted as stacked turbidites. Orientations of: (i) folds; (ii) imbricated mud clasts; (iii) backsets and foresets of climbing ripples; and (iv) asymmetrical convolute lamination were used to determine relative flow directions at the location of the cores. By assigning the basal flow of the stacked debrites and turbidites to the closest principal mass flow, the absolute flow directions of the sub‐deposits were determined which, in combination with multibeam basin‐floor morphology, allowed reconstruction of the 2007 density‐flow successions in Aysén fjord. Furthermore, alternating flow directions provide evidence for a seiche induced by the density flows. It was concluded that X‐ray computed tomography scans provide crucial information for reconstructing palaeoflows and can be a useful tool in marine and lacustrine sedimentology and palaeoseismology. The multidirectionality of sub‐deposits in turbidites is, next to differences in mineralogy, a new criterion to identify stacked turbidites. These multidirectional, stacked turbidites are an indication of simultaneous triggering of density flows and can therefore, in most cases, be attributed to earthquakes, ruling out other triggers, such as floods, storms or other sediment failures.     

A 300-kyr record of aridity and wind strength in southwestern Africa: inferences from grain-size distributions of sediments on Walvis Ridge, SE Atlantic

The terrigenous fraction of sediments recovered from Walvis Ridge, SE Atlantic Ocean, reveals a history of southwestern African climate of the last 300 kyr. End-member modelling of a data set of grain-size distributions (n=428) results in three end members. The two coarsest end members are interpreted as eolian dust, the third end member as hemipelagic mud. The ratio of the two eolian end members reflects the eolian grain size and is attributed to the intensity of the SE trade winds. Trade winds were intensified during glacials compared to interglacials. Changes in the ratio of the two eolian end members over the hemipelagic one are interpreted as variations in southwestern African aridity. Late Quaternary southwestern African climate was relatively arid during the interglacial stages and relatively humid during the glacial stages, owing to meridional shifts in the atmospheric circulation system. During glacials the polar front shifted equatorward, resulting in a northward displacement of the zone of westerlies, causing increased rainfall in southwestern Africa. The equatorward shift of the polar front is coupled with an increase of the meridional pressure gradient, leading to enhanced atmospheric circulation and increased trade-wind intensity.     

Application of a mixing-ratios based formulation to model mixing-driven dissolution experiments

We address the question of how one can combine theoretical and numerical modeling approaches with limited measurements from laboratory flow cell experiments to realistically quantify salient features of complex mixing-driven multicomponent reactive transport problems in porous media. Flow cells are commonly used to examine processes affecting reactive transport through porous media, under controlled conditions. An advantage of flow cells is their suitability for relatively fast and reliable experiments, although measuring spatial distributions of a state variable within the cell is often difficult. In general, fluid is sampled only at the flow cell outlet, and concentration measurements are usually interpreted in terms of integrated reaction rates. In reactive transport problems, however, the spatial distribution of the reaction rates within the cell might be more important than the bulk integrated value. Recent advances in theoretical and numerical modeling of complex reactive transport problems [De Simoni M, Carrera J, Sanchez-Vila X, Guadagnini A. A procedure for the solution of multicomponent reactive transport problems. Water Resour Res 2005;41:W11410. doi: 10.1029/2005WR004056, De Simoni M, Sanchez-Vila X, Carrera J, Saaltink MW. A mixing ratios-based formulation for multicomponent reactive transport. Water Resour Res 2007;43:W07419. doi: 10.1029/2006WR005256] result in a methodology conducive to a simple exact expression for the space–time distribution of reaction rates in the presence of homogeneous or heterogeneous reactions in chemical equilibrium. The key points of the methodology are that a general reactive transport problem, involving a relatively high number of chemical species, can be formulated in terms of a set of decoupled partial differential equations, and the amount of reactants evolving into products depends on the rate at which solutions mix. The main objective of the current study is to show how this methodology can be used in conjunction with laboratory experiments to properly describe the key processes that occur in a complex, geochemically-active system under chemical equilibrium conditions. We model three CaCO₃ dissolution experiments reported in Singurindy et al. [Singurindy O, Berkowitz B, Lowell RP. Carbonate dissolution and precipitation in coastal environments: Laboratory analysis and theoretical consideration. Water Resour Res 2004;40:W04401. doi: 10.1029/2003WR002651, Singurindy O, Berkowitz B, Lowell RP. Correction to Carbonate dissolution and precipitation in coastal environments: laboratory analysis and theoretical consideration. Water Resour Res 2005;41:W11701. doi: 10.1029/2005WR004433], in which saltwater and freshwater were mixed in different proportions. The integrated reaction rate within the cell estimated from the experiments are modeled independently by means of (a) a state-of-the-art reactive transport code, and (b) the uncoupled methodology of [12, 13], both of which use dispersivity as a single, adjustable parameter. The good agreement between the results from both methodologies demonstrates the feasibility of using simple solutions to design and analyze laboratory experiments involving complex geochemical problems.     

Sm–Nd isotopic mapping of lithospheric growth and stabilization in the eastern Kaapvaal craton

Whole-rock Sm–Nd isotope systematics of 79 Archean granitoids from the eastern Kaapvaal craton, southern Africa, are used to delineate lithospheric boundaries and to constrain the timescale of crustal growth, assembly and geochemical differentiation c. 3.66–2.70 Ga. Offsets in ε_Nd values for 3.2–3.3 Ga granitoids across the Barberton greenstone belt (BGB) are consistent with existing models for c. 3.23 Ga accretion of newly formed lithosphere north of the BGB onto pre-existing c. 3.66 Ga lithosphere south of the BGB along a doubly verging subduction margin. The Nd isotopic signature of c. 3.3–3.2 Ga magmatic rocks show that significant crustal growth occurred during subduction–accretion. After c. 3.2 Ga, however, the Nd signature of intrusive rocks c. 3.1 and 2.7 Ga is dominated by intracrustal recycling rather than by new additions from the mantle, signalling cratonic stability.     

Petrographic,fluid inclusion and isotopic study of the Dikulushi Cu–Ag deposit,Katanga (D.R.C.): implications for exploration

The Dikulushi Cu–Ag vein-type deposit is located on the Kundelungu Plateau, in the southeastern part of the Democratic Republic of Congo (D.R.C.). The Kundelungu Plateau is situated to the north of the Lufilian Arc that hosts the world-class stratiform Cu–Co deposits of the Central African Copperbelt. A combined petrographic, fluid inclusion and stable isotope study revealed that the mineralisation at Dikulushi developed during two spatially and temporally distinct mineralising episodes. An early Cu–Pb–Zn–Fe mineralisation took place during the Lufilian Orogeny in a zone of crosscutting EW- and NE-oriented faults and consists of a sequence of sulphides that precipitated from moderate-temperature, saline H₂O–NaCl–CaCl₂-rich fluids. These fluids interacted extensively with the country rocks. Sulphur was probably derived from thermochemical reduction of Neoproterozoic seawater sulphate. Undeformed, post-orogenic Cu–Ag mineralisation remobilised the upper part of the Cu–Pb–Zn–Fe mineralisation in an oxidising environment along reactivated and newly formed NE-oriented faults in the eastern part of the deposit. This mineralisation is dominated by massive Ag-rich chalcocite that precipitated from low-temperature H₂O–NaCl–KCl fluids, generated by mixing of moderate- and low-saline fluids. The same evolution in mineralisation assemblages and types of mineralising fluids is observed in three other Cu deposits on the Kundelungu Plateau. Therefore, the recognition of two distinct types of (vein-type) mineralisation in the study area has a profound impact on the exploration in the Kundelungu Plateau region. The identification of a Cu–Ag type mineralisation at the surface could imply the presence of a Cu–Pb–Zn–Fe mineralisation at depth.     

Methods and code for ‘classical’ age-modelling of radiocarbon sequences

Age–depth models form the backbone of most palaeoenvironmental studies. However, procedures for constructing chronologies vary between studies, they are usually not explained sufficiently, and some are inadequate for handling calibrated radiocarbon dates. An alternative method based on importance sampling through calibrated dates is proposed. Dedicated R code is presented which works with calibrated radiocarbon as well as other dates, and provides a simple, systematic, transparent, documented and customizable alternative. The code automatically produces age–depth models, enabling exploration of the impacts of different assumptions (e.g., model type, hiatuses, age offsets, outliers, and extrapolation).